By Tristram Chivers

ISBN-10: 9812560955

ISBN-13: 9789812560957

A advisor to Chalcogen-Nitrogen Chemistry examines the position of chalcogen-nitrogen compounds in parts starting from solid-state inorganic chemistry to biochemistry. The dialogue covers primary questions about the bonding in electron-rich platforms, in addition to power functional purposes of polymers and fabrics with novel magnetic or electric houses. This e-book is the single account of this significant subject to seem within the final twenty-five years, and paired with its vast literature insurance of very fresh advancements, this complete consultant is vital for a person operating within the box. The therapy is exclusive in delivering a comparability of sulfur, selenium and tellurium structures, with an technique meant to stress basic strategies that might be important to the non-specialist. each one bankruptcy is designed to be self-contained, and there are vast cross-references among chapters.

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H-U. Höfs, J. W. Bats, R. Gleiter, G. Hartman, R. Mews, M. Eckert-0DNVLü H. Oberhammer and G. M. Sheldrick, Chem. , 118, 3781 (1985). 44. P. Del Bel Belluz, A. W. Cordes, E. M. Kristof, P. V. Kristof, S. W. Liblong and R. T. Oakley, J. Am. Chem. , 111, 6147 (1989). 45. E. Hey, C. Ergezinger and K. Dehnicke, Z. , 44B, 205 (1989). 46. (a) V. Chandrasekhar, T. Chivers, J. F. Fait and S. S. Kumaravel, J. Am. Chem. , 112, 5373 (1990); (b) V. Chandrasekhar, T. Chivers, S. S. Kumaravel, M. Parvez and M.

Oakley, Cyclic and Heterocyclic Thiazenes, Prog. Inorg. , 36, 1 (1988). K. F. Preston and L. H. Sutcliffe, ESR Spectroscopy of Free Radicals Containing Sulfur Linked to Nitrogen, Mag. Reson. , 28, 189 (1990). A. W. Cordes, R. C. Haddon and R. T. Oakley, Heterocyclic Thiazyl and Selenazyl Radicals: Synthesis and Applications in Solid-State Architecture, in R. ) The Chemistry of Inorganic Heterocycles, Elsevier, pp. 295-322 (1992). 12 A Guide to Chalcogen–Nitrogen Chemistry A. J. Banister and J. M.

20. 20 40 A Guide to Chalcogen–Nitrogen Chemistry (a) (b) Fig. 4 EPR spectra of (a) [Ph4P2N3S]• and (b) [Ph4P215N3S]• in CH2Cl2 [Reproduced with permission from J. Chem. , Chem. 21, E = S, Se). 21 produces deep blue (E = S) or green (E = Se) solutions in toluene. The EPR spectra of these solutions consist of a septet (1:3:6:7:6:3:1) of decets (Fig. 5). 22 in which the dianion [S(NtBu)3]2- and the radical monoanion [S(NtBu)3] -• are bridged by three Li+ cations. 22 (E = Se, S) Fig. 22, E = S) in toluene at 20°C.

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A Guide to Chalcogen-Nitrogen Chemistry by Tristram Chivers

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